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Set up a dredging station with two bowls. Combine the flour, cornstarch, Chinese 5-spice powder, salt and pepper in one large bowl. Mix the egg and milk together in a second bowl. Dredge the pork cubes in the flour mixture first, then dip them into the egg wash and then back into the flour to coat on all sides. Spray the coated pork cubes with vegetable or canola oil.
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Pre-heat the air fryer to 400ºF.
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Toss the pepper chunks with a little oil and air-fry at 400ºF for 5 minutes, shaking the basket halfway through the cooking time.
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While the peppers are cooking, start making the sauce. Combine the ketchup, rice wine vinegar, brown sugar, orange juice, soy sauce, and garlic in a medium saucepan and bring the mixture to a boil on the stovetop. Reduce the heat and simmer for 5 minutes. When the peppers have finished air-frying, add them to the saucepan along with the pineapple chunks. Simmer the peppers and pineapple in the sauce for an additional 2 minutes. Set aside and keep warm.
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Add the dredged pork cubes to the air fryer basket and air-fry at 400ºF for 6 minutes, shaking the basket to turn the cubes over for the last minute of the cooking process.
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When ready to serve, toss the cooked pork with the pineapples, peppers and sauce. Serve over white rice and garnish with chopped scallions.